“Structural, Spectroscopic, and Quantum-Chemical Characterization of the First Well-Defined Iridium(IV) Oxo Complex: Hydrogen Tunneling in C-H Activation of Dihydroanthracene Influenced by Redox State and Basicity”

https://pubmed.ncbi.nlm.nih.gov/38116899

The first well-defined iridium(IV) oxo complex has been structurally, spectroscopically, and quantum-chemically characterized, revealing that hydrogen tunneling in C-H activation of dihydroanthracene is influenced by the complex’s redox state and basicity.