“Diastereoselective Epimerization of Exocyclic Amines Using Visible Light and Thiyl-Radical Mediated Reversible Hydrogen Atom Transfer”

https://pubmed.ncbi.nlm.nih.gov/38114418

This study describes a new method for diastereoselective epimerization of exocyclic amines using visible light and thiyl-radical mediated reversible hydrogen atom transfer to achieve thermodynamically controlled isomer ratios.